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'All-in-one' tactic for metalla[3]catenanes, Borromean rings and ring-in-ring sophisticated – The Queens County Citizen

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Different interlocked constructions: monomeric rectangle ring-in-ring complex Borromean rings [2]catenanes linear [3]catenanes. Credit score: Science China Push

Interlocked molecular species have been given substantial notice a short while ago, not only simply because of their intriguing structures and topological great importance, but also simply because of their essential apps as molecular equipment and nanoscale units. Benefiting from the reversible coordination bond, some sophisticated interlocked structure could be recognized by large-produce, just one-step procedures, for example, [2]catenanes and Solomon knot. Molecular Borromean rings (BRs) are [3]catenanes topoisomers in which none of the part rings is joined, but also simply cannot be separated without breaking one of the rings (Fig. 1). Linear [3]catenanes are an additional fascinating interlocked 3-ring motif. A number of successful methods for the design of organic linear [3]catenanes have been presented. Having said that, the possible strategies for the synthesis of organometallic linear metalla[3]catenanes dependent on coordination-pushed self-assembly are continue to really unusual. Outside of linear [3]catenanes, ring-in-ring elaborate are also a incredibly rare structural motif, which can be considered as substructures of BRs and vital intermediates for the preparation of BRs.Just lately, Ye Lu, Dong Liu, Yue-Jian Lin, Zhen-Hua Li and Guo-Xin Jin from Fudan University (Shanghai, China) designed exciting progress and produced self-assembly of metalla[3]catenanes, Borromean rings and ring-in-ring intricate making use of a simple π-donor unit.

Thanks to the big electron cloud of the sulfur atom, S-containing heterocyclic compounds ordinarily existing much better stacking interactions than polycyclic aromatic compounds under very similar conditions. In get to boost the stacking interactions, bithiophenyl teams were being applied as making blocks to switch the extensively utilized phenylene or polycyclic aromatic teams. Meantime, electrostatic interactions between electron-loaded (π-donor, D) and electron-deficient (π-acceptor, A) aromatic groups are essential driving forces in host-visitor chemistry. Metallarectangles or cages based mostly on coordination self-assembly generally bear several constructive charges. Because of to Coulombic repulsion, this kind of metallarectangles or cages is extra suited for blend with electroneutral or electron-loaded friends than with electron-very poor cations, and conquering the Coulombic repulsion amongst a cationic visitor and a cationic host is nonetheless a challenge. Bithiophenyl teams are potent D units, so their introduction into metallarectangles could direct to sturdy interactions among D units and A models, which is a promising strategy to overcome the Coulombic repulsion and likely allow for introduction of a positively-charged cation inside a positively-billed cationic metallarectangle. Following this logic, if an electron-deficient cation could be released into a cationic metallarectangle by taking gain of potent D-A interactions, it could also be probable to thread a cationic metallarectangle based mostly on A models inside a metallarectangle centered on D models, to acquire a heterogeneous D-A ring-in-ring advanced.

Solitary-crystal X-ray buildings of [2]catenanes (a), molecular Borromean rings (b) and [3] catenanes (c). Credit history: Science China Push

In this do the job, a collection of Cp*Rh-primarily based (Cp* = pentamethylcyclopentadienyl) homogeneous metalla[2]catenanes, as effectively as linear metalla[3]catenanes and BRs structure ended up recognized via the use of building blocks primarily based on bithiophenyl groups, a straightforward π-donor unit. Bithiophenyl groups enjoy a critical purpose in the development of the homogeneous interlocked structures, namely enhancing the toughness of the inter-ring interactions. By having benefit of powerful electrostatic interactions involving D and A units, the electron-deficient methylviologen cation was used as a guest molecule to notice reversible conversion involving a [2]catenanes and a monomeric rectangle. In addition, a cationic metallarectangle based on A units was threaded inside a metallarectangle centered on bithiophenyl teams, major to a heterogeneous ring-in-ring sophisticated. This method for forming ring-in-ring advanced was extended by use of a metallarectangle dependent on pyrenyl team.

These results will aid the understanding of coordination self-assembly and advance the industry of organometallic assemblies.

&quotAll-in-one&quot strategy for metalla[3]catenanes, borromean rings and ring-in-ring complex
Single-crystal X-ray buildings of ring-in-ring complicated. Credit score: Science China Press

Nano-polycatenane synthesis accomplished with molecular self-assembly


Additional data:
Ye Lu et al, Self-assembly of metalla[3]catenanes, borromean rings and ring-in-ring elaborate using a simple π-donor device, Nationwide Science Evaluation (2020). DOI: 10.1093/nsr/nwaa164
Delivered by
Science China Press

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retrieved 21 August 2020
from https://phys.org/information/2020-08-all-in-one-method-metalla3catenanes-borromean-ring-in-ring.html

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Here’s how Helene and other storms dumped a whopping 40 trillion gallons of rain on the South

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More than 40 trillion gallons of rain drenched the Southeast United States in the last week from Hurricane Helene and a run-of-the-mill rainstorm that sloshed in ahead of it — an unheard of amount of water that has stunned experts.

That’s enough to fill the Dallas Cowboys’ stadium 51,000 times, or Lake Tahoe just once. If it was concentrated just on the state of North Carolina that much water would be 3.5 feet deep (more than 1 meter). It’s enough to fill more than 60 million Olympic-size swimming pools.

“That’s an astronomical amount of precipitation,” said Ed Clark, head of the National Oceanic and Atmospheric Administration’s National Water Center in Tuscaloosa, Alabama. “I have not seen something in my 25 years of working at the weather service that is this geographically large of an extent and the sheer volume of water that fell from the sky.”

The flood damage from the rain is apocalyptic, meteorologists said. More than 100 people are dead, according to officials.

Private meteorologist Ryan Maue, a former NOAA chief scientist, calculated the amount of rain, using precipitation measurements made in 2.5-mile-by-2.5 mile grids as measured by satellites and ground observations. He came up with 40 trillion gallons through Sunday for the eastern United States, with 20 trillion gallons of that hitting just Georgia, Tennessee, the Carolinas and Florida from Hurricane Helene.

Clark did the calculations independently and said the 40 trillion gallon figure (151 trillion liters) is about right and, if anything, conservative. Maue said maybe 1 to 2 trillion more gallons of rain had fallen, much if it in Virginia, since his calculations.

Clark, who spends much of his work on issues of shrinking western water supplies, said to put the amount of rain in perspective, it’s more than twice the combined amount of water stored by two key Colorado River basin reservoirs: Lake Powell and Lake Mead.

Several meteorologists said this was a combination of two, maybe three storm systems. Before Helene struck, rain had fallen heavily for days because a low pressure system had “cut off” from the jet stream — which moves weather systems along west to east — and stalled over the Southeast. That funneled plenty of warm water from the Gulf of Mexico. And a storm that fell just short of named status parked along North Carolina’s Atlantic coast, dumping as much as 20 inches of rain, said North Carolina state climatologist Kathie Dello.

Then add Helene, one of the largest storms in the last couple decades and one that held plenty of rain because it was young and moved fast before it hit the Appalachians, said University of Albany hurricane expert Kristen Corbosiero.

“It was not just a perfect storm, but it was a combination of multiple storms that that led to the enormous amount of rain,” Maue said. “That collected at high elevation, we’re talking 3,000 to 6000 feet. And when you drop trillions of gallons on a mountain, that has to go down.”

The fact that these storms hit the mountains made everything worse, and not just because of runoff. The interaction between the mountains and the storm systems wrings more moisture out of the air, Clark, Maue and Corbosiero said.

North Carolina weather officials said their top measurement total was 31.33 inches in the tiny town of Busick. Mount Mitchell also got more than 2 feet of rainfall.

Before 2017’s Hurricane Harvey, “I said to our colleagues, you know, I never thought in my career that we would measure rainfall in feet,” Clark said. “And after Harvey, Florence, the more isolated events in eastern Kentucky, portions of South Dakota. We’re seeing events year in and year out where we are measuring rainfall in feet.”

Storms are getting wetter as the climate change s, said Corbosiero and Dello. A basic law of physics says the air holds nearly 4% more moisture for every degree Fahrenheit warmer (7% for every degree Celsius) and the world has warmed more than 2 degrees (1.2 degrees Celsius) since pre-industrial times.

Corbosiero said meteorologists are vigorously debating how much of Helene is due to worsening climate change and how much is random.

For Dello, the “fingerprints of climate change” were clear.

“We’ve seen tropical storm impacts in western North Carolina. But these storms are wetter and these storms are warmer. And there would have been a time when a tropical storm would have been heading toward North Carolina and would have caused some rain and some damage, but not apocalyptic destruction. ”

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Follow AP’s climate coverage at https://apnews.com/hub/climate

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Follow Seth Borenstein on Twitter at @borenbears

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Associated Press climate and environmental coverage receives support from several private foundations. See more about AP’s climate initiative here. The AP is solely responsible for all content.

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‘Big Sam’: Paleontologists unearth giant skull of Pachyrhinosaurus in Alberta

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It’s a dinosaur that roamed Alberta’s badlands more than 70 million years ago, sporting a big, bumpy, bony head the size of a baby elephant.

On Wednesday, paleontologists near Grande Prairie pulled its 272-kilogram skull from the ground.

They call it “Big Sam.”

The adult Pachyrhinosaurus is the second plant-eating dinosaur to be unearthed from a dense bonebed belonging to a herd that died together on the edge of a valley that now sits 450 kilometres northwest of Edmonton.

It didn’t die alone.

“We have hundreds of juvenile bones in the bonebed, so we know that there are many babies and some adults among all of the big adults,” Emily Bamforth, a paleontologist with the nearby Philip J. Currie Dinosaur Museum, said in an interview on the way to the dig site.

She described the horned Pachyrhinosaurus as “the smaller, older cousin of the triceratops.”

“This species of dinosaur is endemic to the Grand Prairie area, so it’s found here and nowhere else in the world. They are … kind of about the size of an Indian elephant and a rhino,” she added.

The head alone, she said, is about the size of a baby elephant.

The discovery was a long time coming.

The bonebed was first discovered by a high school teacher out for a walk about 50 years ago. It took the teacher a decade to get anyone from southern Alberta to come to take a look.

“At the time, sort of in the ’70s and ’80s, paleontology in northern Alberta was virtually unknown,” said Bamforth.

When paleontogists eventually got to the site, Bamforth said, they learned “it’s actually one of the densest dinosaur bonebeds in North America.”

“It contains about 100 to 300 bones per square metre,” she said.

Paleontologists have been at the site sporadically ever since, combing through bones belonging to turtles, dinosaurs and lizards. Sixteen years ago, they discovered a large skull of an approximately 30-year-old Pachyrhinosaurus, which is now at the museum.

About a year ago, they found the second adult: Big Sam.

Bamforth said both dinosaurs are believed to have been the elders in the herd.

“Their distinguishing feature is that, instead of having a horn on their nose like a triceratops, they had this big, bony bump called a boss. And they have big, bony bumps over their eyes as well,” she said.

“It makes them look a little strange. It’s the one dinosaur that if you find it, it’s the only possible thing it can be.”

The genders of the two adults are unknown.

Bamforth said the extraction was difficult because Big Sam was intertwined in a cluster of about 300 other bones.

The skull was found upside down, “as if the animal was lying on its back,” but was well preserved, she said.

She said the excavation process involved putting plaster on the skull and wooden planks around if for stability. From there, it was lifted out — very carefully — with a crane, and was to be shipped on a trolley to the museum for study.

“I have extracted skulls in the past. This is probably the biggest one I’ve ever done though,” said Bamforth.

“It’s pretty exciting.”

This report by The Canadian Press was first published Sept. 25, 2024.

The Canadian Press. All rights reserved.

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The ancient jar smashed by a 4-year-old is back on display at an Israeli museum after repair

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TEL AVIV, Israel (AP) — A rare Bronze-Era jar accidentally smashed by a 4-year-old visiting a museum was back on display Wednesday after restoration experts were able to carefully piece the artifact back together.

Last month, a family from northern Israel was visiting the museum when their youngest son tipped over the jar, which smashed into pieces.

Alex Geller, the boy’s father, said his son — the youngest of three — is exceptionally curious, and that the moment he heard the crash, “please let that not be my child” was the first thought that raced through his head.

The jar has been on display at the Hecht Museum in Haifa for 35 years. It was one of the only containers of its size and from that period still complete when it was discovered.

The Bronze Age jar is one of many artifacts exhibited out in the open, part of the Hecht Museum’s vision of letting visitors explore history without glass barriers, said Inbal Rivlin, the director of the museum, which is associated with Haifa University in northern Israel.

It was likely used to hold wine or oil, and dates back to between 2200 and 1500 B.C.

Rivlin and the museum decided to turn the moment, which captured international attention, into a teaching moment, inviting the Geller family back for a special visit and hands-on activity to illustrate the restoration process.

Rivlin added that the incident provided a welcome distraction from the ongoing war in Gaza. “Well, he’s just a kid. So I think that somehow it touches the heart of the people in Israel and around the world,“ said Rivlin.

Roee Shafir, a restoration expert at the museum, said the repairs would be fairly simple, as the pieces were from a single, complete jar. Archaeologists often face the more daunting task of sifting through piles of shards from multiple objects and trying to piece them together.

Experts used 3D technology, hi-resolution videos, and special glue to painstakingly reconstruct the large jar.

Less than two weeks after it broke, the jar went back on display at the museum. The gluing process left small hairline cracks, and a few pieces are missing, but the jar’s impressive size remains.

The only noticeable difference in the exhibit was a new sign reading “please don’t touch.”

The Canadian Press. All rights reserved.

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